Double braid nylon. Better hand than three strand nylon. I would NEVER use a natural fiber line for mooring lines.
Edit: 1/2” diameter DBN is going average 8k WLL. For a mooring or maneuvering line you’ll want the strength to not risk parting, but not the size that brings inelasticity. What makes synthetics more dangerous than natural fiber is also what makes it far superior. You want sudden loading to shockload a cheap piece of cordage, not an expensive piece of deck hardware and fiberglass or metal.